Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes
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چکیده
منابع مشابه
Permanganate Oxidation mechanisms of Alkylarenes
Permanganate oxidation of benzaldehyde and p-nitrobenzaldehyde goes by two paths, i.e. a major one which is responsible for the normal oxidation giving good second order kinetic and minor path which involves a very small percent of a radical species formed by hydrogen atom abstraction by the permanganate ion. A mechanism involving Hydrogen atom abstraction by permanganate from the alkoxide ion ...
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The observation of Manchot? that sodium pentacyano-ammineferroate2 I absorbs oxygen has led Baudisch and his coworkers3 to study the catalytic action of this salt, as well as of its water analogue II, in the oxidation of pyrimidines and purines. The present authors have previously reported in this journal4 on the nature of the oxidation products obtained. In the present paper the problem is con...
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2019
ISSN: 2041-1723
DOI: 10.1038/s41467-019-10414-7